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Tetrahedron
Volume 49, Issue 41, 1993, Pages 9333-9342
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doi:10.1016/0040-4020(93)80019-P    
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Copyright © 1993 Published by Elsevier Science Ltd. All rights reserved.

Alkaloids of the Mexican Bean Beetle, Epilachna varivestis (Coccinellidae)*1, , *2

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Athula B. Attygalle, *, Shang-Cheng Xu1, Kevin D. McCormick and Jerrold Meinwald

Curtis L. Blankespoor and Thomas Eisner

Baker Laboratory, Department of Chemistry, Cornell University, Ithaca, New York 14853 U.S.A.

Section of Neurobiology and Behavior, Cornell University, Ithaca, New York 14853 U.S.A.


Received 12 March 1993; 
accepted 30 March 1993. 
Available online 12 March 2001.

Abstract

Two novel alkaloids, 2-(12-aminotridecyl)-pyrrolidine and its 1-(2-hydroxyethyl) derivative, are characterized from extracts of adult Mexican bean beetles. These pyrrolidines, together with a previously identified homotropane alkaloid, euphococcinine, account for 90% of the alkaloids present in this beetle. A number of piperidine derivatives are also identified as minor components. The total mixture represents the most complex bouquet of alkaloids reported hitherto from any coccinellid beetle.

Graphical Abstract

Several new alkaloids, including 2-(12-aminotridecyl)-pyrrolidine (G) and its l-(2- hydroxyethyl) derivative (I), are characterized from extracts of adult Mexican bean beetles.

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Article Outline

• References

*1 This publication is dedicated to Prof. Carl Djerassi on the ocassion of his seventieth birthday.

*2 Paper no. 119 in the series “Defense Mechanisms of Arthropods.”

1 Permanent address: Jiangsu Pesticide Research Institute, Nanjing 210036, People's Republic of China.


Tetrahedron
Volume 49, Issue 41, 1993, Pages 9333-9342
Result list | previous < 134 of 166 > next 
 
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